Electrochemistry for materials science /

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Bibliographic Details
Author / Creator:	Plieth, W. (Waldfried)
Edition:	1st ed.
Imprint:	Amsterdam ; Boston : Elsevier, 2008.
Description:	xxi, 410 p. : ill. ; 25 cm.
Language:	English
Subject:	Electrochemistry. Materials -- Electric properties. Electrochemistry, Industrial. Electrochemistry. Electrochemistry, Industrial. Materials -- Electric properties.
Format:	Print Book
URL for this record:	http://pi.lib.uchicago.edu/1001/cat/bib/6686378

Hidden Bibliographic Details
ISBN:	9780444527929 (hbk.) 0444527923 (hbk.)
Notes:	Includes bibliographical references and index.

Table of Contents:

List of Symbols
Preface
1. Electrolytes
1.1. Liquid Electrolyte Solutions
1.2. Ionic Melts
1.2.1. Alkali halide melts
1.2.2. Glass forming molten salts
1.2.3. Ionic liquids
1.3. Ionic Conductance in Polymers
1.3.1. Polymer electrolytes
1.3.2. Gel polymer electrolytes
1.3.3. Ion exchanging polymer electrolytes
1.4. Ionic Conductance in Solids
1.4.1. Crystal defects
1.4.2. Intrinsic disorder
1.4.3. Extrinsic disorder
1.4.4. Disorder in sub-lattices
1.4.5. Transport by defects
1.4.6. Ion conducting glasses
1.4.7. Mixed ionic and electronic conductance
2. Structure and Bonding
2.1. Structure Factors
2.2. Closed Packed Structures of Metals
2.3. Alloys with Closed Packed Structure
2.4. Hume-Rothery Rules for Formation of Solid Solutions
2.5. Body Centered Cubic Structure
2.6. Hume-Rothery Phases
2.7. Ionic Structures
2.8. Coordination Polyhedrons of Molecules
2.9. The Band Model of Electrons in Solids
2.9.1. Free electrons in a metal
2.9.2. Orbitals in solids
2.9.3. Density of states (DOS)
2.9.4. Filling up with electrons; Fermi energy
2.9.5. Crystal orbital overlap population: the formation of bonds
2.9.6. Extension to more dimensions
2.9.7. Band structure of d-metals
2.9.8. Semiconductors: example TiO[subscript 2]
2.9.9. Peierls distortion
2.9.10. Energy bands in electrolytes
2.10. Cohesion in Solids
2.10.1. Lattice enthalpy
2.10.2. Sublimation enthalpy
2.10.3. Bond energies of metals
2.10.4. Bond energies of alloys
3. Electrode Potentials
3.1. Pure Metals
3.1.1. Equilibrium between a metal phase and an electrolyte phase
3.1.2. Standard electrode potentials
3.1.3. Standard electrode potentials of metal complexes
3.2. Alloys
3.2.1. Partial molar Gibbs energies
3.2.2. Electrochemical measurements of partial molar functions
3.2.3. Ag[subscript x]Au[subscript y]-example of a solid solution
3.2.4. Partial molar functions of component B
3.2.5. From partial molar functions to integral functions
3.3. Intermetallic Phases and Compounds
3.3.1. Potential versus mole fraction diagrams
3.3.2. Coulometric titration
3.3.3. Coulometric titration: the system LiAl
3.3.4. Intermetallic compounds: the system LiSb
3.3.5. Measurements at room temperatures: CuZn
4. Ad-Atoms and Underpotential Deposition
4.1. The Thermodynamic Description of the Interphase
4.1.1. The electrochemical double layer
4.1.2. Ideally polarizable electrodes
4.1.3. Electrocapillary curves
4.1.4. Adsorption isotherms
4.1.5. Reversible electrodes
4.1.6. Partial charge and electrosorption valency
4.1.7. Thermodynamics of solid electrolyte interfaces
4.2. Principal Methods for the Investigation of the Electrochemical Double Layer
4.2.1. Measurement of capacitance
4.2.2. Cyclic voltammetry and chronoamperometry
4.2.3. Determination of the adsorbed mass
4.2.4. Scanning tunneling microscopy and related methods
4.3. Ad-Atoms
4.3.1. Adsorption and desorption of ad-atoms
4.3.2. Equilibrium ad-atom concentration
4.3.3. Surface diffusion of ad-atoms
4.4. Underpotential Deposition
4.4.1. Lead on silver
4.4.2. Copper on Au
4.4.3. Underpotential deposition as two-dimensional phase formation
4.4.4. Multiple steps of UPD film formation
5. Mass Transport
5.1. Stationary Diffusion
5.2. Non-Stationary Diffusion
5.2.1. Chronopotentiometry
5.2.2. Chronoamperometry, chronocoulometry
5.2.3. Warburg impedance
5.2.4. Cyclic voltammetry
5.2.5. Microelectrodes
5.3. Diffusion in Solid Phases
5.3.1. Potentiostatic method
5.3.2. Galvanostatic method
5.4. Methods to Control Diffusion Overpotential
5.4.1. Rotating-disc electrode
5.4.2. Rotating ring-disc electrodes
5.4.3. Rotating-cylinder electrodes
6. Charge Transfer
6.1. Electron Transfer
6.1.1. Butler-Volmer equation
6.1.2. Tafel lines
6.1.3. Charge transfer resistance
6.1.4. Theories of electron transfer
6.2. Electrochemical Reaction Orders
6.2.1. Determination of electrochemical reaction orders from Tafel lines
6.2.2. Determination of electrochemical reaction orders from the charge transfer resistance
6.3. Ion Transfer
6.4. Charge Transfer and Mass Transport
6.4.1. Elimination of diffusion overpotential with a rotating disc electrode
6.4.2. Elimination of diffusion contribution to the overpotential in chronoamperometry and chronopotentiometry
6.4.3. Elimination of diffusion contributions to the overpotential by impedance spectroscopy
7. Nucleation and Growth of Metals
7.1. Nucleation
7.1.1. Three-dimensional nucleation
7.1.2. Two-dimensional nucleation
7.1.3. Rate of nucleation
7.1.4. Instantaneous and progressive nucleation
7.2. Intermediate States of Electrodeposition
7.2.1. Crystallization overpotential
7.3. Surface Dynamics
7.3.1. Residence time in kink site positions
7.3.2. Calculation of the residence time
7.4. Density of Kink Site Positions
7.4.1. Equilibrium conditions
7.4.2. Deposition conditions
7.5. Experimental Investigations of Electrodeposition
7.5.1. Electrodeposition on amalgam electrodes
7.5.2. Investigations on solid electrodes
7.5.3. Applications of electrodeposition from aqueous solvents
7.5.4. Parallel reactions
7.6. Deposition From Non-Aqueous Solvents
7.6.1. Aluminum deposition from a molten salt
7.6.2. Aluminum deposition from an organic electrolyte
7.6.3. Aluminum deposition from ionic liquids
7.7. Additives
7.7.1. Adsorption, the hard-soft concept
7.7.2. Influence of additives on deposition at different crystallographic faces
7.7.3. Anodic stripping to study additive behavior
7.8. Optical Spectroscopy to Study Metal Deposition
7.8.1. Raman spectroscopy on silver in cyanide electrolytes
7.8.2. Raman spectroscopy of organic additives
8. Deposition of Alloys
8.1. Deposition Potential and Equilibrium Potential
8.2. Alloy Nucleation and Growth: The Partial Current Concept
8.3. Brenner's Alloy Classification
8.4. Mixed Potential Theory
8.5. Surface Selectivity in Alloy Deposition
8.5.1. Kink site positions of alloys
8.5.2. Rate of separation and residence times
8.5.3. Residence time and structure of alloys
8.6. Markov Chain Theory; Definition of the Probability Matrix
8.6.1. Equilibrium of the crystallization process
8.6.2. Rate controlled processes
8.6.3. Determination of selectivity constants
8.6.4. Alloy characterization by selectivity constants
8.6.5. Selectivity constants and residence times in kink site positions
8.7. Experimental Examples
8.7.1. The cobalt-iron alloy system
8.7.2. Cobalt-nickel
8.7.3. Iron-nickel
8.7.4. Induced electrodeposition: the NiMo system
8.8. Ternary Systems
8.8.1. Kink site positions of ternary systems
8.8.2. The Markov chain theory for ternary systems
8.8.3. Example: prediction of the composition of CoFeNi alloys
9. Oxides and Semiconductors
9.1. Electrochemical Properties of a Semiconductor
9.1.1. Band model of a semiconductor
9.1.2. Semiconductor-electrolyte contact
9.1.3. Gap states and surface states
9.1.4. Current-potential curves
9.1.5. Space-charge capacitance
9.2. Photoelectrochemistry of Semiconductors
9.2.1. Photocurrents
9.2.2. Intensity modulated photocurrent spectroscopy (IMPS)
9.2.3. Photopotentials and photopotential transients
9.3. Spectroscopic Methods
9.3.1. In situ spectroscopic methods
9.3.2. In situ X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS)
9.3.3. In situ Mossbauer spectroscopy
9.3.4. Ex situ methods
9.4. Microscopy
9.5. Oxide Particles
9.5.1. Batteries
9.5.2. Lithium ion batteries
9.5.3. TiO[subscript 2]-based photovoltaic cells
9.5.4. Catalytic activity of oxide particles
9.6. Oxide Layers
9.7. Electrochemical Deposition of Semiconductors
10. Corrosion and Corrosion Protection
10.1. Corrosion
10.1.1. Fundamental processes
10.1.2. Mechanism of metal dissolution
10.1.3. Mechanisms of compensation reactions
10.1.4. Iron and steel
10.1.5. Metallurgical aspects of iron and steel
10.1.6. Copper
10.1.7. Zinc
10.1.8. Corrosion products
10.1.9. Corrosion of alloys
10.2. Corrosion Protection
10.2.1. Passivity
10.2.2. Cathodic protection
10.2.3. Corrosion inhibition
10.2.4. Phosphatizing
10.2.5. Chromatizing
10.2.6. Corrosion protection by surface coatings
11. Intrinsically Conducting Polymers
11.1. Chemical Synthesis
11.2. Electrochemical Synthesis and Surface Film Formation
11.3. Film Formation with Adhesion Promoters
11.4. Ion Transport During Oxidation-Reduction
11.4.1. Analyzing oxidation-reduction cycles using QCMB
11.5. Electrical and Optical Film Properties
11.5.1. Impedance of conducting polymers
11.5.2. Neutral state properties
11.5.3. Photoelectrochemical properties
11.5.4. Polaron-bipolaron model of conducting polymers
11.5.5. Spectro-electrochemical methods
11.6. Copolymerization
11.6.1. Mechanism of copolymerization
11.6.2. Structure analysis of copolymers
11.6.3. Properties of copolymers
11.7. Corrosion Protection by Intrinsically Conducting Polymers
11.7.1. Film formation on non-noble metals
11.7.2. Kinetic experiments of corrosion protection
11.7.3. Role of anions for a possible corrosion protection of conducting polymers
12. Nanoelectrochemistry
12.1. Going to Atomic Dimensions
12.2. Co-Deposition
12.2.1. Particle dispersions
12.2.2. Determination of the zeta potential
12.2.3. Factors influencing zeta potential and particle properties
12.2.4. Properties of the metal surface
12.2.5. Process parameters influencing the incorporation
12.2.6. Mechanistic models
12.2.7. General concepts for the development of a model
12.2.8. Examples
12.3. Compositionally Modulated Multi-Layers
12.3.1. Plating of multi-layers
12.3.2. Examples of multi-layers
12.4. Core-Shell Composites
12.4.1. Preparation procedure
12.4.2. Particle characterization: applications
Index

Electrochemistry for materials science /

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