Polymer phase diagrams : a textbook /

Polymer phase diagrams : a textbook /

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Bibliographic Details
Author / Creator:Koningsveld, R. (Ronald)
Imprint:Oxford ; New York : Oxford University Press, 2001.
Description:xvii, 341 p. : ill. ; 26 cm.
Language:English
Subject:
Polymers.
Plastics.
Phase diagrams.
Phase diagrams.
Plastics.
Polymers.
Format: Print Book
URL for this record:http://pi.lib.uchicago.edu/1001/cat/bib/4430532
Hidden Bibliographic Details
Other authors / contributors:Stockmayer, W. H. (Walter H.)
Nies, E. (Erik)
ISBN:0198556357 (acid free paper)
0198556349 (pbk. : acid free paper)
Notes:Includes bibliographical references (p. [325]-337) and index.
Table of Contents:
  • Preface
  • Glossary of symbols and abbreviations
  • Part 1. Principles of Heterogeneous Equilibrium
  • 1. Single-component systems
  • 1.1. Thermodynamic laws
  • 1.2. Conditions for equilibrium between phases
  • 1.3. Equilibrium curves
  • 1.4. Further remarks on the p(T) diagram
  • 1.5. Vapour/liquid equilibrium: p(V) diagram
  • 1.6. Supercooling; first- and second-order phase transitions
  • 1.7. Exercises
  • 2. Mixtures
  • 2.1. Chemical potentials
  • 2.2. The phase rule
  • 2.3. Exercises
  • 3. Binary systems, Bakhuis Roozeboom diagram
  • 3.1. Phase rule
  • 3.2. Two-phase equilibria
  • 3.3. Three-phase equilibrium
  • 3.4. The Bakhuis Roozeboom p(T, x[subscript 2]) space diagram; phase diagrams
  • 3.5. Rules for equilibrium curves and metastable extensions
  • 3.6. Supercooling and vitrification
  • 3.7. Exercises
  • 4. Binary systems, partial miscibility in the liquid phase, and supercritical phenomena
  • 4.1. Introduction
  • 4.2. Liquid/liquid equilibrium
  • 4.3. Bakhuis Roozeboom diagram with a partially miscible liquid phase
  • 4.4. Solid/liquid/liquid equilibrium
  • 4.5. Supercritical phenomena; solubility enhancement
  • 4.6. Exercises
  • 5. Binary systems, solid solutions, and compounds
  • 5.1. Solid solutions
  • 5.2. Compounds
  • 5.3. Exercises
  • 6. Ternary and multicomponent systems
  • 6.1. Introduction
  • 6.2. Partial miscibility
  • 6.3. Crystalline phases
  • 6.4. Appearance of vapour phases
  • 6.5. Exercises
  • Part 2. Simple Modelling
  • 7. Modelling partial miscibility and solid/liquid equilibrium
  • 7.1. Introduction
  • 7.2. Liquid/liquid equilibrium
  • 7.3. Solid/liquid equilibrium
  • 7.4. Exercises
  • Part 3. Heterogeneous Equilibrium in Macromolecular Systems
  • 8. Introduction
  • 8.1. General remarks
  • 8.2. Free enthalpy of mixing
  • 8.3. Exercises
  • 9. Partial miscibility of strictly binary polymer systems
  • 9.1. Introduction
  • 9.2. Demixing of strictly binary systems
  • 9.3. Binary polymer solutions
  • 9.4. Binary polymer mixtures (blends)
  • 9.5. Determination of cloud points
  • 9.6. Blends containing statistical copolymers
  • 9.7. Upper and lower critical miscibility (UCST and LCST)
  • 9.8. Exercises
  • 10. Partial miscibility of quasi-binary polymer systems
  • 10.1. General principles
  • 10.2. Quasi-binary polymer solutions
  • 10.3. Equilibrium among three liquid phases
  • 10.4. Quasi-binary polymer blends
  • 10.5. The theta temperature
  • 10.6. Exercises
  • 11. The influence of pressure
  • 11.1. Introduction
  • 11.2. Vapour/liquid equilibrium involving polymer solutions
  • 11.3. Liquid/liquid equilibrium in the absence of vapour
  • 11.4. Exercises
  • 12. Solid/liquid equilibrium
  • 12.1. Introduction
  • 12.2. Solid/liquid equilibrium in homopolymer systems
  • 12.3. Interference of solubility curve and miscibility gap
  • 12.4. Other factors
  • 12.5. Copolymers
  • 12.6. Exercises
  • 13. (Quasi-)ternary polymer systems
  • 13.1. Introduction
  • 13.2. Two solvents, one polymer
  • 13.3. One solvent, two polymers
  • 13.4. Three polymers
  • 13.5. Exercises
  • 14. Fractionation of polymers
  • 14.1. Introduction
  • 14.2. Fractionation by distribution among two liquid phases
  • 14.3. Fractional crystallization and dissolution
  • 14.4. Fractionation by size-exclusion chromatography
  • 14.5. Exercises
  • 15. Miscellaneous phase transitions
  • 15.1. Introduction
  • 15.2. Mesophases; block copolymers
  • 15.3. Mesophases; liquid-crystalline polymers
  • 15.4. Equilibrium swelling of networks
  • 15.5. Glass transition
  • 15.6. Flow
  • 15.7. Thin films
  • Appendix 1. Spinodals and critical points
  • Appendix 2. Simple modelling for small-molecule systems
  • A2.1. Introduction
  • A2.2. Eutectic behaviour
  • A2.3. Partial miscibility
  • A2.4. Compounds
  • Appendix 3. Calculation of cloud-point, shadow, and coexistence curves in macromolecular systems
  • A3.1. Molar-mass distributions
  • A3.2. Coexistence conditions for (quasi-)binary systems
  • A3.3. Coexistence conditions for (quasi-)ternary systems
  • A3.4. Alternative procedures
  • Appendix 4. Simple modelling of equilibria in polymeric systems
  • A4.1. Introduction
  • A4.2. Practically binary polymer solutions
  • A4.3. Polymer blends
  • A4.4. Quasi-binary liquid-crystalline polymer systems
  • Appendix 5. Numerical evaluation of interaction parameters
  • A5.1. Introduction
  • A5.2. Concentration and molar-mass dependence
  • A5.3. Solubility parameters
  • A5.4. Chemical potentials
  • A5.5. Higher derivatives of [Delta]G
  • A5.6. Sedimentation equilibrium
  • A5.7. (Quasi-)ternary systems
  • A5.8. Copolymers
  • A5.9. Interface analysis
  • Appendix 6. Molecular basis of the interaction parameter
  • Answers to exercises
  • References
  • Index
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