Polymer phase diagrams : a textbook /
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Author / Creator: | Koningsveld, R. (Ronald) |
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Imprint: | Oxford ; New York : Oxford University Press, 2001. |
Description: | xvii, 341 p. : ill. ; 26 cm. |
Language: | English |
Subject: | |
Format: | Print Book |
URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/4430532 |
Table of Contents:
- Preface
- Glossary of symbols and abbreviations
- Part 1. Principles of Heterogeneous Equilibrium
- 1. Single-component systems
- 1.1. Thermodynamic laws
- 1.2. Conditions for equilibrium between phases
- 1.3. Equilibrium curves
- 1.4. Further remarks on the p(T) diagram
- 1.5. Vapour/liquid equilibrium: p(V) diagram
- 1.6. Supercooling; first- and second-order phase transitions
- 1.7. Exercises
- 2. Mixtures
- 2.1. Chemical potentials
- 2.2. The phase rule
- 2.3. Exercises
- 3. Binary systems, Bakhuis Roozeboom diagram
- 3.1. Phase rule
- 3.2. Two-phase equilibria
- 3.3. Three-phase equilibrium
- 3.4. The Bakhuis Roozeboom p(T, x[subscript 2]) space diagram; phase diagrams
- 3.5. Rules for equilibrium curves and metastable extensions
- 3.6. Supercooling and vitrification
- 3.7. Exercises
- 4. Binary systems, partial miscibility in the liquid phase, and supercritical phenomena
- 4.1. Introduction
- 4.2. Liquid/liquid equilibrium
- 4.3. Bakhuis Roozeboom diagram with a partially miscible liquid phase
- 4.4. Solid/liquid/liquid equilibrium
- 4.5. Supercritical phenomena; solubility enhancement
- 4.6. Exercises
- 5. Binary systems, solid solutions, and compounds
- 5.1. Solid solutions
- 5.2. Compounds
- 5.3. Exercises
- 6. Ternary and multicomponent systems
- 6.1. Introduction
- 6.2. Partial miscibility
- 6.3. Crystalline phases
- 6.4. Appearance of vapour phases
- 6.5. Exercises
- Part 2. Simple Modelling
- 7. Modelling partial miscibility and solid/liquid equilibrium
- 7.1. Introduction
- 7.2. Liquid/liquid equilibrium
- 7.3. Solid/liquid equilibrium
- 7.4. Exercises
- Part 3. Heterogeneous Equilibrium in Macromolecular Systems
- 8. Introduction
- 8.1. General remarks
- 8.2. Free enthalpy of mixing
- 8.3. Exercises
- 9. Partial miscibility of strictly binary polymer systems
- 9.1. Introduction
- 9.2. Demixing of strictly binary systems
- 9.3. Binary polymer solutions
- 9.4. Binary polymer mixtures (blends)
- 9.5. Determination of cloud points
- 9.6. Blends containing statistical copolymers
- 9.7. Upper and lower critical miscibility (UCST and LCST)
- 9.8. Exercises
- 10. Partial miscibility of quasi-binary polymer systems
- 10.1. General principles
- 10.2. Quasi-binary polymer solutions
- 10.3. Equilibrium among three liquid phases
- 10.4. Quasi-binary polymer blends
- 10.5. The theta temperature
- 10.6. Exercises
- 11. The influence of pressure
- 11.1. Introduction
- 11.2. Vapour/liquid equilibrium involving polymer solutions
- 11.3. Liquid/liquid equilibrium in the absence of vapour
- 11.4. Exercises
- 12. Solid/liquid equilibrium
- 12.1. Introduction
- 12.2. Solid/liquid equilibrium in homopolymer systems
- 12.3. Interference of solubility curve and miscibility gap
- 12.4. Other factors
- 12.5. Copolymers
- 12.6. Exercises
- 13. (Quasi-)ternary polymer systems
- 13.1. Introduction
- 13.2. Two solvents, one polymer
- 13.3. One solvent, two polymers
- 13.4. Three polymers
- 13.5. Exercises
- 14. Fractionation of polymers
- 14.1. Introduction
- 14.2. Fractionation by distribution among two liquid phases
- 14.3. Fractional crystallization and dissolution
- 14.4. Fractionation by size-exclusion chromatography
- 14.5. Exercises
- 15. Miscellaneous phase transitions
- 15.1. Introduction
- 15.2. Mesophases; block copolymers
- 15.3. Mesophases; liquid-crystalline polymers
- 15.4. Equilibrium swelling of networks
- 15.5. Glass transition
- 15.6. Flow
- 15.7. Thin films
- Appendix 1. Spinodals and critical points
- Appendix 2. Simple modelling for small-molecule systems
- A2.1. Introduction
- A2.2. Eutectic behaviour
- A2.3. Partial miscibility
- A2.4. Compounds
- Appendix 3. Calculation of cloud-point, shadow, and coexistence curves in macromolecular systems
- A3.1. Molar-mass distributions
- A3.2. Coexistence conditions for (quasi-)binary systems
- A3.3. Coexistence conditions for (quasi-)ternary systems
- A3.4. Alternative procedures
- Appendix 4. Simple modelling of equilibria in polymeric systems
- A4.1. Introduction
- A4.2. Practically binary polymer solutions
- A4.3. Polymer blends
- A4.4. Quasi-binary liquid-crystalline polymer systems
- Appendix 5. Numerical evaluation of interaction parameters
- A5.1. Introduction
- A5.2. Concentration and molar-mass dependence
- A5.3. Solubility parameters
- A5.4. Chemical potentials
- A5.5. Higher derivatives of [Delta]G
- A5.6. Sedimentation equilibrium
- A5.7. (Quasi-)ternary systems
- A5.8. Copolymers
- A5.9. Interface analysis
- Appendix 6. Molecular basis of the interaction parameter
- Answers to exercises
- References
- Index