Studies on palladium catalyzed functionalization of indoles, synthesis of piperazines and rhodium catalyzed binol arylation /
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| Author / Creator: | Montgomery, Thomas David, author. |
|---|---|
| Imprint: | 2015. Ann Arbor : ProQuest Dissertations & Theses, 2015 |
| Description: | 1 electronic resource (680 pages) |
| Language: | English |
| Format: | E-Resource Dissertations |
| Local Note: | School code: 0330 |
| URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/10773417 |
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| 100 | 1 | |a Montgomery, Thomas David, |e author. | |
| 245 | 1 | 0 | |a Studies on palladium catalyzed functionalization of indoles, synthesis of piperazines and rhodium catalyzed binol arylation / |c Montgomery, Thomas David. |
| 260 | |c 2015. | ||
| 264 | 1 | |a Ann Arbor : |b ProQuest Dissertations & Theses, |c 2015 | |
| 300 | |a 1 electronic resource (680 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 500 | |a Advisors: Viresh H. Rawal Committee members: Jared C. Lewis; Scott A. Snyder. | ||
| 502 | |b Ph.D. |c The University of Chicago, Division of the Physical Sciences, Department of Chemistry |d 2015. | ||
| 506 | |a This item is not available from ProQuest Dissertations & Theses. | ||
| 510 | 4 | |a Dissertation Abstracts International, |c Volume: 77-05(E), Section: B. | |
| 520 | |a The synthesis and functionalization of basic heterocyclic compounds remains an important field in organic chemistry. Through the use of a palladium catalyst both indoles and oxindoles were combined with ally, benzyl and propargyl carbonates to generate new heterocycles in good yield. Propargyl carbonates could also be combined with diamines in the presence of a palladium catalyst to generate piperazines and other related heterocylces. The use of rhodium was explored for the ortho functionalization of binaphthols and novel asymmetric hydrogen bonding catalysts were synthesized and tested with a number of different transformations. | ||
| 546 | |a English | ||
| 590 | |a School code: 0330 | ||
| 690 | |a Organic chemistry. | ||
| 690 | |a Chemistry. | ||
| 710 | 2 | |a University of Chicago. |e degree granting institution. | |
| 720 | 1 | |a Viresh H. Rawal |e degree supervisor. | |
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