Studies on palladium catalyzed functionalization of indoles, synthesis of piperazines and rhodium catalyzed binol arylation /

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Bibliographic Details
Author / Creator:Montgomery, Thomas David, author.
Imprint:2015.
Ann Arbor : ProQuest Dissertations & Theses, 2015
Description:1 electronic resource (680 pages)
Language:English
Format: E-Resource Dissertations
Local Note:School code: 0330
URL for this record:http://pi.lib.uchicago.edu/1001/cat/bib/10773417
Hidden Bibliographic Details
Other authors / contributors:University of Chicago. degree granting institution.
ISBN:9781339321103
Notes:Advisors: Viresh H. Rawal Committee members: Jared C. Lewis; Scott A. Snyder.
This item is not available from ProQuest Dissertations & Theses.
Dissertation Abstracts International, Volume: 77-05(E), Section: B.
English
Summary:The synthesis and functionalization of basic heterocyclic compounds remains an important field in organic chemistry. Through the use of a palladium catalyst both indoles and oxindoles were combined with ally, benzyl and propargyl carbonates to generate new heterocycles in good yield. Propargyl carbonates could also be combined with diamines in the presence of a palladium catalyst to generate piperazines and other related heterocylces. The use of rhodium was explored for the ortho functionalization of binaphthols and novel asymmetric hydrogen bonding catalysts were synthesized and tested with a number of different transformations.
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520 |a The synthesis and functionalization of basic heterocyclic compounds remains an important field in organic chemistry. Through the use of a palladium catalyst both indoles and oxindoles were combined with ally, benzyl and propargyl carbonates to generate new heterocycles in good yield. Propargyl carbonates could also be combined with diamines in the presence of a palladium catalyst to generate piperazines and other related heterocylces. The use of rhodium was explored for the ortho functionalization of binaphthols and novel asymmetric hydrogen bonding catalysts were synthesized and tested with a number of different transformations. 
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