Organometallic and chemoenzymatic approaches to arene arylation via C-H bond cleavage /

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Bibliographic Details
Author / Creator:Durak, Landon J., author.
Ann Arbor : ProQuest Dissertations & Theses, 2015
Description:1 electronic resource (172 pages)
Format: E-Resource Dissertations
Local Note:School code: 0330
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Other authors / contributors:University of Chicago. degree granting institution.
Notes:Advisors: Jared C. Lewis Committee members: Chuan He; Richard F. Jordan.
Dissertation Abstracts International, Volume: 77-02(E), Section: B.
Summary:This dissertation describes organometallic and chemoenzymatic efforts to synthesize biaryl compounds via C-H bond cleavage. A key goal of these efforts is to achieve site-selectivities that are different from the bulk of contemporary C-H functionalization methods. Toward this end, methods involving site-selectivity derived from steric effects between a substrate and catalyst and through supramolecular control are described.

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