Organometallic and chemoenzymatic approaches to arene arylation via C-H bond cleavage /
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Author / Creator: | Durak, Landon J., author. |
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Imprint: | 2015. Ann Arbor : ProQuest Dissertations & Theses, 2015 |
Description: | 1 electronic resource (172 pages) |
Language: | English |
Format: | E-Resource Dissertations |
Local Note: | School code: 0330 |
URL for this record: | http://pi.lib.uchicago.edu/1001/cat/bib/10773224 |
Other authors / contributors: | University of Chicago. degree granting institution. |
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ISBN: | 9781339079684 |
Notes: | Advisors: Jared C. Lewis Committee members: Chuan He; Richard F. Jordan. Dissertation Abstracts International, Volume: 77-02(E), Section: B. English |
Summary: | This dissertation describes organometallic and chemoenzymatic efforts to synthesize biaryl compounds via C-H bond cleavage. A key goal of these efforts is to achieve site-selectivities that are different from the bulk of contemporary C-H functionalization methods. Toward this end, methods involving site-selectivity derived from steric effects between a substrate and catalyst and through supramolecular control are described. |
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